Search results for "gas [monitoring]"
showing 10 items of 492 documents
ChemInform Abstract: Reversal of Asymmetric Induction in Stereoselective Strecker Synthesis on Galactosyl Amine as the Chiral Matrix.
1989
Abstract The reversal of the direction of asymmetric induction in Lewis acid catalyzed Strecker synthesis using the 2,3,4,6-tetra-O-pivaloyl-β-D-galactopyranosyl amine 1 is described. In isopropanol or tetrahydrofuran 1 had given ( R )-diastereomers of the corresponding α-amino nitriles preferably. However, in chloroform in the presence of heterogeneous zinc chloride the same auxiliary alternatively leads to an excess of the ( S )-diastereomers.
Ethyl 1-acetyl-3-amino-1H-pyrazole-4-carboxylate, a tetragonal structure with Z′ = 4
2006
The title compound, C8H11N3O3, crystallizes with Z' = 4. One pyrazole N atom is substituted and excluded from intermolecular contacts. The amine N, acetyl O and an ester O atom are involved in the formation of nearly planar molecular layers. The layers are perpendicular to the c axis, with an interlayer distance of 3.333 Å. The hydrogen-bonding patterns are similar for each molecule, i.e. intramolecular N-H...O, as well as intermolecular N-H...O and C-H...N(pyrazole), bonds are present.
Ietekmējošie faktori vecāku lēmumu pieņemšanai meiteņu vakcinācijai pret cilvēka papilomas vīrusu
2019
Bakalaura darba tēma – Ietekmējošie faktori vecāku lēmumu pieņemšanai meiteņu vakcinācijai pret cilvēka papilomas vīrusu. Tēmas aktualitāti nosaka zema cilvēka papilomas vīrusa vakcinācijas aptvere Latvijā. Vecāku lēmumu pieņemšana vakcinācijas jautājumos ir daudzfaktoru komplekss, kuru var ietekmēt vecāku zināšanas un attieksme pret vakcināciju, plašsaziņu līdzekļi, veselības speciālistu sniegtās rekomendācijas. Darba mērķis ir noskaidrot ietekmējošos faktorus vecāku lēmumu pieņemšanai meiteņu vakcinācijai pret cilvēka papilomas vīrusu. Pētniecības uzdevumi ir izpētīt zinātnisko literatūru par faktoriem, kas ietekmē vecāku lēmumu pieņemšanu meiteņu vakcinācijai pret cilvēka papilomas vīrus…
Crystal structure and magnetic properties of (tris{4-[1-(2-methoxyethyl)imidazol-2-yl]-3-azabut-3-enyl}amine)iron(II) bis(hexafluoridophosph…
2019
The title compound, [Fe(C27H41N10O3)](PF6)2, is an example of an iron(II) spin-crossover compound. In this compound, C⋯F and CH⋯F/O contacts, present between the cations and anions, extend the structure into a three-dimensional supramolecular network.
N-Methyl-4-(4-nitrophenyl)-N-nitroso-1,3-thiazol-2-amine
2017
The title compound, C10H8N4O3S, is almost planar [dihedral angle between the rings = 2.2 (2)°; r.m.s. deviation for the non-H atoms = 0.050 Å]. In the crystal, C—H...O and C—H...N hydrogen bonds link the molecules into (10-2) layers.
{Bis[2-(diisopropylphosphanyl)ethyl]amine}carbonyl(tetrahydroborato)cobalt(I)
2018
In the structure of title borohydride pincer complex, [Co(BH4)(C16H37NP2)(CO)], the cobalt(I) metal exhibits a distorted square-pyramidal coordination geometry with the basal positions occupied by the P and N atoms of the tridentate ligand and by the C atom of the carbon monoxide ligand. In the crystal, molecules interact only by van der Waals forces.
4,4′-(1,2-Diazaniumylethane-1,2-diyl)dibenzoate trihydrate
2016
The title compound, C16H16N2O4·3H2O, was synthesized from (1R,2R)-1,2-bis(2-hydroxyphenyl)ethylenediamine and terephthalaldehydic acid. The compound crystallizes from water as a double zwitterion with protonated amine groups and deprotonated carboxylate groups. The dihedral angle formed by the aromatic rings is 3.86 (11)°. In the crystal, N—H...O and O—H...O hydrogen bonds link molecules into a three-dimensional network.
Crystal structure of (E)-2-(tert-butylamino)-4-(tert-butylimino)naphthalen-1(4H)-one
2018
The title compound is the first example of a naphthoquinone imine derivative crystallizing in the 4-imine/2-amine tautomeric form having bulky tert-butyl substituents at the N atoms.
Low energy calibration, continuous monitoring, and background studies for the NEXT-White detector at the LSC
2021
Los neutrinos han sido una puerta a grandes cambios en los paradigmas del entendimiento de la naturaleza, y aún tienen preguntas que responder en las próximas décadas. El descubrimiento de la oscilación de neutrinos implica que éstos son partículas con masa. Esta masa abre la cuestión de su origen, es decir, si son fermiones de Dirac o de Majorana. La potencial naturaleza de Majorana puede arrojar luz en temas abiertos como la baja escala de masas de los neutrinos con respecto a los demás fermiones, así como la asimetría entre materia y antimateria observada actualmente en el universo. De entre todas las posibles formas de discernir la naturaleza última de los neutrinos, la más madura y des…
Unusual Regioselectivity in the Opening of Epoxides by Carboxylic Acid Enediolates
2008
Addition of carboxylic acid dianions appears to be a potential alternative to the use of aluminium enolates for nucleophilic ring opening of epoxides. These conditions require the use of a sub-stoichiometric amount of amine (10% mol) for dianion generation and the previous activation of the epoxide with LiCl. Yields are good, with high regioselectivity, but the use of styrene oxide led, unexpectedly, to a mixture resulting from the attack on both the primary and secondary carbon atoms. Generally, a low diastereoselectivity is seen on attack at the primary center, however only one diastereoisomer was obtained from attack to the secondary carbon of the styrene oxide.